@InProceedings{MungerMaDaKiArGaWo:2002:VaCaMo,
author = "Munger, J. William and Matross, Daniel M. and Dauber, Bruce C. and
Kirchhoff, Volker Walter Johann Heinrich and Artaxo, Paulo and
Gatti, Luciana Vanni and Wofsy, Steven C.",
title = "Variations in carbon monoxide concentrations at a Central
Amazonian site",
year = "2002",
organization = "International LBA Scientific Conference, 2.",
keywords = "GEOF{\'{\I}}SICA ESPACIAL.",
abstract = "Carbon Monoxide (CO)plays a major role in controlling the global
levels of OH in the atmosphere, and is a tracer of combustion
sources. CO measurements are being made at a forested site near
Santarem, Para, Brazil (km67 tower site)in order to determine
background CO levels in the clean continental tropical atmosphere,
to identify factors that control CO levels, and to serve as a
tracer for emissions from local and distant biomass burning. A CO
measurement system consisting of a Thermo Environmental
Instruments model 48CTL analyzer, cold-trap at 2.5C to eliminate
variations in water vapor interference, zeroing catalyst, and
automated calibration with 100 and 500 nmol mol-1 standards was
installed in April, 2001. Sample is drawn from an inlet above the
forest canopy. CO concentrations were less than 100 nmol mol-1 on
average, with no ignificant diel variation during the rainy
season, April to June. The wet season data indicate a low regional
background CO concentration and suggest that the local forest is
neither a significant source nor sink for CO. In mid July, after
local rain ended, there was a modest increase in CO concentration
that was not accompanied by a large increase variance. This
increase we attribute to increased transport from distant CO
sources or to increased production by photochemistry of biogenic
hydrocarbons contributing to regional enhancement in CO. In late
August, the variability of CO concentrations begins to increase
dramatically. Individual half-hour concentrations exceed 1000 nmol
mol-1. By November, the frequency and magnitude of high CO events
has increased. Maximum concentrations up to 5000 nmol mol-1 are
observed and the minimum concentrations have increased to about
200 nmol mol-1. The high CO levels and large variability are due
to nearby fires. The diel variation during the late dry season
when local fires are present shows a strong enhancement during the
night as smoke is trapped in the nocturnal boundary layer. CO
concentrations drop sharply after January 1, 2002 when heavy rains
put an end to local burning. CO during the burning season will be
used as a tracer to quantify the contribution by fires to CO2
variability and to determine emission factors for aerosol
components.",
conference-location = "Manaus, Br",
conference-year = "7-10 July 2002",
label = "10274",
targetfile = "munger_variations.pdf",
urlaccessdate = "04 maio 2024"
}